How reliable are CO2 measurements?
The skeptic argument...
CO2 measurements are suspect
"The Keeling curve, which is widely used to show the increase in CO2 emissions, is based on data from the top of Mount Mauna Loa in Hawaii. Mauna Loa is a volcano and it doesn’t seem to me that a volcano is the best place to be taking CO2 measurements" (disinter)
What the science says...
The following graph shows atmospheric CO2 levels over the last 10,000 years. It includes ice core data for CO2 levels before 1950. For values after 1950, direct measurements from Mauna Loa, Hawaii were used.

Figure 1: CO2 levels (parts per million) over the past 10,000 years. Blue line from Taylor Dome ice cores (NOAA). Green line from Law Dome ice core (CDIAC). Red line from direct measurements at Mauna Loa, Hawaii (NOAA).
Mauna Loa is often used as an example of rising carbon dioxide levels because its the longest, continuous series of directly measured atmospheric CO2. The reason why it's acceptable to use Mauna Loa as a proxy for global CO2 levels is because CO2 mixes well throughout the atmosphere. Consequently, the trend in Mauna Loa CO2 (1.64 ppm per year) is statistically indistinguishable from the trend in global CO2 levels (1.66 ppm per year). If global CO2 was used in Figure 1 above, the result "hockey stick" shape would be identical.

Figure 2: Global atmospheric CO2 (NOAA) versus Mauna Loa CO2 (NOAA).
The following video is a graphic example of where our data for CO2 levels comes from. It shows surface measurements of CO2 varying over different latitudes from 1979 to 2006. The graph is created by Andy Jacobson from the NOAA and includes a global map displaying where the measurements are coming from, a comparison of Mauna Loa CO2 to South Pole CO2 and the graph expands at the end to include ice core measurements back to the 19th Century.
Satellite data is consistent with surface measurements and present a fuller picture of global CO2 concentration. The next video shows global distribution of mid-tropospheric carbon dioxide. This data comes from the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua spacecraft. Superiposed over the global map is a graph of carbon dioxide observed at the Mauna Loa observatory.
Last updated on 9 July 2010 by John Cook.

Arguments






























As it happens, there are many sources of CO2 contamination. Not only are there cars, factories and people in abundance in cities, all busily emitting CO2 in abundance, and consequently contaminating any measurement. Not only that, but trees and grass are net CO2 sinks in daylight, but net emitters of CO2 at night. Consequently measurements in a forest on a still night will show elevated CO2 levels, again the result of contamination.
In the 1850s, and indeed, even in the 1930s this was not well known, and many measurements of CO2 concentrations were made in areas where contamination would be expected. What is worse, Beck, who should have known better compiled a list of measurements without compensating for local contamination beyond the crudest measure, and simply took an average of measurements to determine the CO2 concentration. Given that CO2 concentrations can vary by 100 ppmv or more on a daily basis due to local contamination, the result significantly overestimates background CO2 levels.
To determine genuine background levels of CO2, you need to get away from local sources of CO2 emission by getting either very far away from their source vertically, as with these measurements over Colorado:
Note that near ground concentrations shown can be as high as much as 50 ppmv above the upper altitude levels even at 500 meters altitude (let alone the 2 meter altitude used by Beck), but with gain in altitude, CO2 concentrations drop to background levels.
Alternatively you can rely on strong winds to dilute the contamination to determine the background by plotting CO2 levels against wind speed:
Again, notice when wind velocities are low, local contamination (mostly from forests in this case) can result in CO2 concentrations as high as 600 ppmv, but that the background level is clearly around 390 ppmv.
Or you can get as far away geographically from any contamination as you can, by going to the South Pole:
Citing measurements that do not take these precautions to ensure they are measuring the genuine background concentrations, rather than a contaminated sample are, of course of no interest.
Please note how easily and completely you fell for what is actually a well understood "lie". You read at a denial site about how CO2 levels were way higher in the 1800s and there's a paper to prove it. Except it turns out that everyone who cares to actually be skeptical and look at the science knows that's nonsense. Scientists go to great lengths to properly, accurately measure CO2, and they aren't stupid about it. At the same time, the paper cited by deniers to trumpet this issue was literally stupid about it.
They know this. This information is readily available, and it's pretty obvious if you take just a little while to think about it. So why do denial sites keep feeding people this nonsense?
The point is that you were tricked, and you came in here all full of anger because you thought the ones who tricked you were the scientists. But it wasn't, it was the deniers.
[Fortunately, this site exists exactly because of those sorts of situations. Every time you have one of these "ah ha, got them" moments by reading something at a nonsense denier site, come here to SkS, use the search button, read and learn. After you've done it enough, you'll start to realize that there is no science or truth to the denial arguments. None.]
So how do you feel now? Is your anger redirected at a more appropriate target? Or are you instead simply more firmly invested in finding something to justify your anger at "alarmists?"
And if the latter is the case... doesn't that say something even more important about the "debate."
Take the hint from Tom Curtis and Sphaerica - you are, to put it nicely, profoundly in error.
If the conversation here is too technical for you, there was a more colloquial one on Deltoid, that should make you blush with embarrassment once you've read through it.
Jim Eager's comment of 6:21 AM, April 11th 2012:
danielc's comment of 6:33 AM, April 11th 2012:
For comparison, here is the full Keeling Curve from Mauna Loa: