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Murry Salby's Correlation Conundrum

Posted on 5 July 2012 by Dikran Marsupial

Prof. Murry Salby of the Department of Environment and Geography at Macquarie Universiry in Sydney gave a talk last year (August 3, 2011) to the Sydney Institute (described at Wikipedia), in which he claimed that the rise in atmospheric CO2 is not driven by anthropogenic emissions. The abstract of the talk is as follows:

Atmospheric Science, Climate Change and Carbon – Some Facts

Carbon dioxide is emitted by human activities as well as a host of natural processes. The satellite record, in concert with instrumental observations, is now long enough to have collected a population of climate perturbations, wherein the Earth-atmosphere system was disturbed from equilibrium. Introduced naturally, those perturbations reveal that net global emission of CO2 (combined from all sources, human and natural) is controlled by properties of the general circulation – properties internal to the climate system that regulate emission from natural sources. The strong dependence on internal properties indicates that emission of CO2 from natural sources, which accounts for 96 per cent of its overall emission, plays a major role in observed changes of CO2Independent of human emission, this contribution to atmospheric carbon dioxide is only marginally predictable and not controllable.

Naturally the talk stirred considerable interest in the blogsphere (e.g. at Climate Etc.).  More recently, a video of this talk was made available, so we can now investigate Prof. Salby's argument in more detail.


Why we can be Confident that Prof. Salby's Conclusions are Incorrect

Ironically, the first 11 minutes of the talk provide all the components required to show beyond reasonable doubt that anthropogenic emissions are responsible for 100% of the observed increase in atmospheric CO2 and that natural sources do not play a major role. At 08:39, Prof. Salby correctly states that

"What is relevant is net emissions, net collected from all sources and sinks, human and natual, that is what ultimately controls atmospheric CO2"

This is then supported by a slide (at 8:58) containing an equation that will be familiar to those that have followed the discussion of earlier claims that the rise in atmospheric CO2 is a natural phenomenon at SkS, for example my rebuttal of Prof. Essenhigh's residence time argument.

This is known as the mass balance equation, and it simply states that as the carbon cycle obeys the principle of conservation of mass, the annual increase in atmospheric CO2 is equal to the difference between total emissions from all sources (both natural and anthropogenic) and the total uptake from all sinks (natural and anthropogenic, although the anthropogenic sink is essentially zero as we are not yet performing significant amounts of carbon sequestration).

For convenience, we can re-write Prof. Salby's mass balance equation in the form

C' = Ea + En - Un,

where Ea represents annual carbon emissions from anthropogenic sources (fossil fuel use and land use change), En represents the carbon emissions from all natural sources (the oceans, soil respiration, volcanos etc.) and Un represent the uptake of carbon by all natural carbon sinks (oceans, photosynthesis, etc.).  C' represents the net emissions rate, which as Prof. Salby says is approximately equal to growth rate of global mean atmospheric CO2.

The problem is then that we don't know the values of En and Un with any real certainty as our knowledge of the natural carbon cycle is limited.  However, we do have good knowledge of anthropogenic emissions, Ea, as Prof. Salby says (at 7:53)

"In truth only one component of the CO2 budget is known with any certainty, human emissions, implicitly through records of extraction - how much coal and oil are dug up"

There are also good records of emissions due to land use changes as well.  We also have reliable observations of the growth rate of CO2 in the atmosphere, as Prof. Salby says (10:35)

"That [CO2 being well mixed in the atmosphere] is a good thing because it means that local values are good approximations of the global average, which in turn provides a record of net global emissions.  In fact we have a long record of CO2 from only one site in the free atmosphere, Mauna Loa Hawaii.  The local record from Mauna Loa therefore approximates the global mean, which through its growth rate chronicles the history of net global emissions, collectively from all sources, human and natural."

In other words we can reliably work out the net emission rate from the Mauna Loa CO2 record by computing the annual growth in atmospheric CO2, i.e. C'.

This allows us to find out something interesting about the natural carbon cycle:  The mass balance equation can be rearranged to give an estimate of the difference between annual emissions from all natural sources and annual natural uptake by all natural sinks.

En - Un = C' - Ea

While we don't know the values of En or Un, the difference between them is constrained by conservation of mass to be the same as the difference between C' and Ea, which we do know!  More importantly if we knew the right hand side of this equation was negative, then we would know that the left hand side must also be negative, so whatever their actual values, Un > En.

O.K., so if we look at the data (for details, see Cawley, 2011), we find that the annual rise in atmospheric CO2 has been less than anthropogenic emisssions every year for at least the last fifty.  We therefore can also be sure that the natural environment has been a net carbon sink, taking in more carbon than it has emitted, every year for the last fifty.  As the natural environment is known to be a net carbon sink, far from being the cause of the observed rise in atmospheric CO2, it has been actively opposing it!

illustration of CO2 mass balance

Figure 1: Results of the mass balance analysis.

This analysis is based on three assumptions:

  1. The carbon cycle obeys the principle of conservation of mass (i.e. the annual growth in atmospheric CO2 is approximately equal to the net emission rate, which is the difference between emissions from all sources and uptake by all sinks).
  2. We know anthropogenic emissions, Ea, with reasonable certainty.
  3. We can reliably estimate the net emissions rate, C', from the Mauna Loa atmospheric CO2 record.

The rest is just trivial algebra.  Prof. Salby has explicitly accepted all three of these assumptions in the quotes presented above taken from his Sydney Institute talk, but unfortunately did not see the natural conclusion arising from those (very reasonable) assumptions.  We know with high certainty that the rise in atmospheric CO2 is not a natural phenomenon and is 100% anthropogenic (at least since 1959).

Prof. Salby's Argument

Prof. Salby's argument appears to be based on an observed correlation between net global emissions (estimated from the Mauna Loa CO2 observations) and "surface conditions", a combination of MSU temperature and soil moisture, as shown in the figure below, from the slide at 17:52 in the Sydney institute talk.

 

Figure 2: Correlation between net global CO2 emissions and the component due to "surface conditions" (temperature and soil moisture).

 The correlation is indeed impressive, clearly there is a relationship between net global emissions and the component due to "surface conditions".  Prof. Salby then determines the contribution to atmospheric CO2 by calculating the cumulative sum of the component due to "surface conditions, which appears to explain essentially all but the annual cycle in the Mauna Loa observations, as shown in this figure from 20:53 in the video.

 

Figure 3: The component of the increase in atmospheric CO2 attributed by Prof. Salby to "circulation dependent component"

 The flaw in this argument is quite subtle, and lies in the fact that the bulk of the long term increase in atmospheric CO2 is due to the mean value of net global emissions, and correlations do not depend on the mean value.  Essentially the correlation only explains the variability of CO2 measurements around the long term trend, but not the trend itself.  Sadly, Prof. Salby's presentation did not include nearly enough information to reproduce the graphs shown above, so I will explain the flaw in his reasoning first via a simple thought experiment, and then illustrate the mainstream understanding of this issue, that is based on the correlation between the annual growth rate and the El Nino Southern Oscillation (ENSO), which was first mentioned in the peer reviewed literature way back in 1979.

 A Simple Gedankenexperiment

Let us assume for the moment that the CO2 observations are composed of a linear component due to anthropogenic emissions, rising at a constant 1.5 ppmV per year, plus a sinusoidal component that was due to the effects of "surface conditions", with a period of five years, such that

C(t) = 1.5*t + 0.5*cos(2*pi*t/3)*sin(2*pi*t/5) - 2630

The numbers are chosen such that the resulting CO2 observations superficially resemble those of the real world (except for the seasonal variation which is not relevant to the thought experiment).

Figure 4: Synthetic atmospheric CO2 observations for thought experiment

Following Prof. Salby's method, we then take the annual differences to estimate the net global emissions:

 

Figure 5: Net global emission derived from synthetic CO2 observations shown in Figure 4.

So far, so good, our synthetic net global emissions are similar to Prof. Salby's in that there is an average value of about 1.5 ppm per year, but superimposed on top of that there is an oscillatory behaviour that sometimes reduces net global emissions almost (but not quite) to zero, and sometimes means that net global emissions are much higher than average.

Happily, as this is a synthetic thought-experiment, we can work out the natural contribution to net global emissions analytically, and we get this:

 

Figure 6: Natural contribution to net global emissions.

Which looks very much like net global emission, and if we compute the correlation between the two then we get a value of 1, i.e. a perfect correlation!  This means we can conclude that the natural component "explains" 100% of the variability in net global emission - obviously we are onto something here!

So, again following Prof. Salby's methodology, we compute the cumulative sum of the natural contribution to net global emission, which gives us the natural contribution to the increase in observed CO2, which gives us this:

Figure 7: Natural contribution to the long term increase in atmospheric CO2.

Oh...., that doesn't look very much like the result obtained by Prof. Salby; the natural component doesn't seem to explain the long term increase at all, even though it is perfectly correlated with the net global emission!

So what is going on?  Well if we compare net global emission (Fig. 5) with the natural contribution to net global emission (Fig. 6), they are identical, except for their mean values.  The mean value of net global emission is about 1.5 ppmv per year, and for the natural contribution it is zero.  When we compute the cumulative sum of the natural contribution, the positive values cancel with the negative values, so the cumulative sum stays near zero.  Thus we can see that the long term rise is principally because of the mean value of net global emission, not because of the wiggles.  Why doesn't the correlation reveal this?  Here is the formula for the sample correlation (courtesy of Wikipedia):

where xand y represent samples from net global emissions and the natural component respectively.  They important thing to notice is that the mean (x or y with a bar over the top) is subtracted from x and y wherever they appear in the equation.  This means that the value of the correlation is the same no matter what the mean values of x and y are.  Thus the correlation doesn't tell you very much about the cause of the long term rise, because that is mainly due to the mean value, not the variablity around the mean.

Next, let's perform the same exercise for the anthropogenic component of the net global emission, which is just 1.5 ppmV per year.

Figure 8: Anthropogenic contribution to net global emission.

If we compute the cumulative sum of the anthropogenic contribution to net global emission, we get the component of the observed increase in CO2 that is due to anthropogenic emissions, which is a steady linear trend rising at 1.5 ppmv per year.

Figure 9: Anthropogenic contribution to the long term increase in atmospheric CO2.

Which clearly does a much better job of explaining the long term trend in atmsopheric CO2, even though the correlation between the anthropogenic component and net global emission is precisely zero!

Key Point: It isn't the variability (the general up and down wiggliness) in net emissions that gives rise to the long term trend, it is the mean value of the net emissions, and the value of the correlation does not depend in any way on the mean value.  Therefore the correlation with net global emission tells you very little about the cause of the long term trend.

What does Mainstream Science say about all this?

It is well known that the annual growth rate of CO2 appears to be influenced by the El Nino Southern Oscillation (ENSO); this correlation was first noticed by Bacastow more than thirty years ago (Bacastow, 1979), and has been widely discussed since then.  The effect of ENSO however is not principally due to changes in sea surface temperatures, but the effect of ENSO on the terrestrial biosphere: According to Jones et al (2001).

"Climatic changes over land during El Nino events lead to decreased gross primary productivity and increased plant and soil respiration, and hence the terrestrial biosphere becomes a source of CO2 to the atmosphere. Conversely, during El Nino events, the ocean becomes a sink of CO2 because of reduction of equatorial Paci?c outgassing as a result of decreased upwelling of carbon-rich deep water. During La Nina events the opposite occurs; the land becomes a sink and the ocean a source of CO2."

It seems possible that the effects of temperature and soil moisture investigated by Prof. Salby are essentially a proxy for ENSO as ENSO affects both temperature and precipitation in the Americas and Australasia.

Prof Salby suggests that the IPCC were not aware of the variability in growth rate discussed in his presentation (29:30):

"The climate modelling framework just described [i.e. one based on the assumption that CO2 levels are predictable] is the cornerstone of the IPCC, ..., I used to be a reviewer.  Much of the public debate stems from the IPCC's last report; the behaviour you have seen was not known at the time of that report".

However, these interannual changes in the carbon cycle are discussed in section 7.3.2.4 of the IPCC AR4 WG1 report.  This states that the variability of fossil fuel emissions and estimated variability in net ocean uptake are too small to account for this signal and is therefore thought to be due to year-to-year fluctuations in the land-atmosphere fluxes.  Furthermore. it states that high CO2 growth rates correspond to El Nino conditions and conversely low growth rates with La Nina conditions.  An additional period (1992-3) of low growth rate followed the eruption of Mount Pinatubo in 1991.  References are also provided to support various lines of evidence confirming that the variability of CO2 fluxes is mostly due to land fluxes.

Notes

I have sent several emails to Prof. Salby asking for clarification on the methods he used in the work described in his Sydney Institute talk, but so far I have had no reply.

Updated 10/09/2015 to fix broken link to Jones (2001).

References

Bacastow, R.B.  1976.  Modulation of atmospheric carbon dioxide by the Southern Oscillation.  Nature 261: 116-118. (www)

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Comments 51 to 66 out of 66:

  1. Tom, a good point about your scenario is that at least in that case atmospheric CO2 levels would still be rising (albeit with a delay of a year or so) even if there were no anthropogenic emissions. That could be used as a reasonable definition of "causing the increase" (although in that case, the mass balance argument would correctly show that to be the case). But then taking in more CO2 than you emit is also a reasonable defintion of "opposing the increase", so in your scenario the natural environment is both "causing" and "opposing" the increase in atmospheric CO2! Perhaps the problem lies in language, rather than science?
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  2. Dikran Marsupial @50 and @51: Clearly we are talking past each other to an extent. You take the Mass Balance argument to infer from the fact that C'-Ea is negative that En < Un, which is indeed deductive. I take the argument to include the additional inference that the rise in CO2 levels is anthropogenic, which is inductive. Using your terminology we would say the Mass Balance argument is a deductive argument that supports a further inductive inference, but I prefer my terminology as it is that further inference which really interests us (or at least me). I agree that your financial analogy is relevant, but as you appear to realize in your 51, the language of causation is such that, regardless of that analogy it could be said that the increase in natural emissions. If we used Hume's rules to clarify the situation, we would say that En is both a necessary and sufficient condition for the increase, so that it is the cause of the increase; but that En is not sufficient for the early timing of the increase, so that only En + Ea together can be considered the cause of the earlier timing of the increase.
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  3. Tom@52 - I would say that the step from En < Un is not inductive, but merely what is for me one reasonable definition of "opposing the increase" rather than "causing the increase". Would you agree that if Un > En that the natural environment could reasonably be said to be "opposing the rise"? I also agree with what you say about Humes rules, and I agree with the conclusions, under that definition of causality , I agree that the mass balance argument is insufficient (I have done some work on probabilistic causal reasoning in the past, so I understand what you are saying). Having said which, it is questionable as to whether En can be treated as a separate entity from Un in assigning causality. If we are concerned with attributing the rise to anthropogenic and natural influences then surely En and Un should only be considered together as they jointly describe "natural influences". However, as the financial analogy shows, that definition of causality isn't necessarily the correct one. In the financial examples, my deposits are also a necessary and sufficient condition for the rise, so for Hume I would be the cause of the rise. But on the other hand most would recognise that my deposits are not the cause of the rise in the balance, and that actually I am syphoning money out for my own benefit (and hence reducing the rate of the rise). I note however here I am not separating En from Un and are consdering them together, whereas you are only considering En in isolation. I should add that I am finding this a very useful and productive discussion; many thanks Tom for your efforts so far.
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  4. Dikran @53, consider the model where, initialy: Ea = 0; En = k; and Un = k + 1.1Ea, where the later relationship is a strict causal relationship. That is, increasing Ea above zero is a necessary and sufficient condition to increase Un above k, and will always increase Un to 1.1Ea + K. Suppose also the En(t+1) = 2En(t)-En(t-1) + Rand, where Rand is a random number between 1 and -1, except that where this would cause En < k, En = k. Finally, suppose that Ea varies in the same way that En does, except that its "floor" is 0 rather than k. In this model: 1) If En = k + 0.1 Ea, C'= 0 2) If En < k + 0.1 Ea, C'< 0 3) If En > k + 0.1 Ea, C'> 0 4) If k + 0.1 Ea < En < k + 1.1 Ea, C'>0 so that the CO2 concentration is increasing, but your mass balance argument is satisfied, ie, En < Un. In this situation, that En > k + 0.1 Ea is a necessary and sufficient condition for the C' > 0. Therefore it is the cause of the increase in CO2 concentration even when the mass balance argument is satisfied. Further, because there is a causal link between Ea and Un, increasing Ea always opposes the increase in CO2 concentration because it directly results in a still greater increase in Un. Therefore, on those few occasions when the mass balance argument is satisfied in this model, you would still not be entitled to say that an rise in CO2 is due to anthropogenic emissions. Would you be able to say the combined effect of Un and En oppose the increase when the mass balance argument is satisfied? Yes - but I think that is a very technical point which doesn't really address the question that we are interested in (what causes CO2 concentrations to increase). Should we treat Un and En as separate entities in assigning causality in this model? Yes, without question. I think this model shows that if you define "opposes the increase" such that it is true whenever Un > En, you have deprived the term of its intuitive relation to assertions about causality. It sounds like you are saying that Un + En do not cause the increase; but there are conditions where it is true that Un + En "oppose the increase" under that definition, but in which Un + En cause the increase because En is the sole and sufficient cause of the increase and hence En + x causes the increase for all x. We can in fact set up this model very easily in your financial analogy. Just add the following two facts to the analogy: a) Whenever I feel like investing, I steal a sum of money from your wallet, deduct 9% for my personal expenses, and invest the remainder; and b) Whenever you have an unexplained shortfall in your wallet, you make up the lost money by withdrawing it from the joint account. These together set up the direct link between Ea and Un; and change the whole situation. Given these additional facts, nobody would doubt that you, not I am responsible for the full increase in our joint account even during those times when your withdrawals exceed your deposits. Of course, developing a scenario like this for CO2 would require incredible contrivance or the assigning of magical properties to CO2. I apologize if this is confusing, or if I have confused myself (which is quite likely) as it is late here and I am quite tired. I look forward to seeing if what I just wrote still makes sense to me tomorrow.
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  5. Hi Tom, I'll have to give the example a lot more thought (and simulate it a bit on my computer - adding stochastic behaviour and temporal correlation makes it very much more difficult to think about). However I have a few observations from my first reading: You write "doesn't really address the question that we are interested in (what causes CO2 concentrations to increase). Should we treat Un and En as separate entities in assigning causality in this model? Yes, without question." For me the real question is "is the rise anthropogenic, or is it natural, or is it both?". Thus to me it makes no sense to consider En separately from Un, as the effect of the natural environment on atmospheric CO2 depends solely on the net flux. This is one point where I am in complete agreement with Prof Salby - it is net emissions that affect CO2 concentrations. It is important to consider En separately from Un if you are interested in the origin of the molecules comprising the excess over equilibrium level, but that is not at all the same question. I think this model shows that if you define "opposes the increase" such that it is true whenever Un > En, you have deprived the term of its intuitive relation to assertions about causality. I disagree. It may be that this definition does not fit with assertions about causality in a theory of knowledge/philosophy of science sense, but I would say those are hardly intuitive. It fits in very well with normal everyday intuition about causality, as my financial example shows. I would prefer to stick with the original financial example until we have reached and understanding about why we appear to disagree about whether I am causing or opposing the rise in the balance. IT may be that causality may be easier to assign in your extended analogy, but then again it is a different analogy, so it still doesn't explain the contradiction exposed by the first. Essentially it seems to me that your are asking whether the increase is caused by natural emissions, whereas I am asking whether the rise is caused by the natural environment (including its response to anthropogenic emissions). These are not the same question, and it is the latter that is relevant to climate change as far as I can see. I'll run your new scenario through the computer and get back to you once I have understood it.
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  6. The pre-bunking of Prof. Salby's yet to appear article applies equally well to the new paper by Humlum et al., who make exactly the same mistake of using a correlation between rates to justify conclusions about long term changes.
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  7. That Humlum et al. 2012 paper is discussed in a new post at RealClimate.
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  8. Ugg. As I stated at RC, I honestly do not understand how that Humlum paper gets through peer review with that interpretation intact. It such an elementary error in interpretation to think the correlation explains the mean value in annual CO2 change. And it's not as if it isn't well know that ocean pCO2 is increasing, stable isotopes of atmospheric CO2 have changed and we can't account for all anthro emissions. How can anyone think the ocean is a source of CO2 given that fact? Who reviews these things? I really think Rasmus was too deferential in his evaluation at RC. Sometimes short and direct is the best policy. Long winded rebuttal suggest that there is some meat there.
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  9. I agree that Rasmus's evaluation at RealClimate was too deferential. I'm not sure why he bothers, to be honest. Some papers are so obviously bad that they seem ludicrous to even comment on. Salby's is certainly in that league. If someone ever actually is able to show that the recent rise in CO2 is not anthopogenic, it will be on the cover of Nature, Science, Quaternary Research and Physics today simultaneously, and I will be the first to write to the Nobel Committee encouraging them to award the prize. Until those things happen, papers making such claims can safely be assumed to be not worth reading.
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  10. An excellent comment at RC by Christoffer Bugge Harder, pointing out the failure by Humlum et al. to account for carbon isotope ratios and C02 uptake in the ocean that can only be termed as blatant disagreement with their hypothesis. Comment is here. Harder's final suggestion applies to a number of scientists who have compromised themselves over AGW. The scientific community as a whole could be of better assistance to the public in evaluating outlandish claims. Crank or liar? Sometimes choices funnel down uncomfortably tight; charitable instincts suggest the former as opposed to the latter.
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  11. Murray Salby recently was not continued in his position at an Australian university, for reasons having nothing to do with his bad science.  DeSmogBlog now reports that several years ago Salby was banned from getting further funding from the U.S. National Science Foundation, for non-science reasons.  The reasons include not reporting financial conflicts of interest (I'm shocked!).

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  12. Thanks for patience with a very basic question:

    If the earth system is a net sink for CO2, and if human contribution prior to the industrial revolution was insignifigant, then shouldnt the long term trend of atmospheric CO2 prior to that point in time be headed towards zero ?  But that is not what our historical data shows is it ?  Or would it head towards a steady state where whatever is produced is constantly being completely absorbed (averaged over the long run)?  But again is that what the historical record shows ?  Thanks.

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  13. InnocentSmithReturns - The earth system is a net sink now, as it accomodates the extra fossil CO2 we've put into the carbon cycle. If we were to stop emitting CO2 right now, that sink would draw atmospheric CO2 down to perhaps 20-35% over pre-industrial levels over several centuries, to the point where the oceans, biosphere, and atmosphere exchange rates balance. Longer term processes such as weathering and CaCO3 formation would draw down the remainder over perhaps 3-7 thousand years. This is the "long tail" commitment we're making with our current emissions. 

    See Archer et al 2009 for a discussion of this topic. 

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  14. "If the earth system is a net sink for CO2, and if human contribution prior to the industrial revolution was insignifigant, then shouldnt the long term trend of atmospheric CO2 prior to that point in time be headed towards zero ? "

    No, the carbon cycle has feedback mechansims that tend to increase the amount of CO2 in the atmosphere and others that tend to decrease it.  So if you leave the carbon cycle to its own devices, it eventually finds an equilibrium atmospheric concentration and stays fairly constant (which is what we observe in the ice core records, during interglacials, the level returns to more or less the same level each time).  However, if you do something to upset the balance (e.g. fossil fuel emissions), then the various feedback mechanisms tend to act to try and return the atmospheric levels back to normal (this is apparently known as LeChatellier's principle).  The reason natural emissions and uptake are out of balance is because anthropogenic emissions have perturbed the previously stable equilibrium.  In pre-industrial times, natural emissions and natural uptake were approximately balanced, and so atmospheric CO2 levels were relatively stable.

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  15. BTW from figure 1, you can see that the net natural sink has been growing over time, which suggests that the net natural sink is a response to increasing anthropogenic emissions.  If you extrapolate backwards I suggest you will find that the net natural sink would hit zero sometime in the 19th century.  In reality a small net natural sink has been in existence for rather longer, but the rate of increase isn't exactly linear, so the extrapolation doesn't give a precise estimate.

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  16. Dikran pointed me here

    Salby is at it again this year with a new presentation with slightly different yet still deeply flawed arguments.  https://youtu.be/sGZqWMEpyUM

    This is the same guy who wrote the textbooks "Physics of the Atmosphere and Climate" and "Fundamentals of Atmospheric Physics".  Based on his contrarian nature when it comes to fundamental science, one has to call into question everything he has written. Same goes for Lindzen, I am finding.

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  17. I think that Dikran Marsupial's mass balance argument is fundamentally flawed. Here is why, based on his mass conservation equation referred to a certain period of time.

    dC = Ea + En - Un

    dC = increase of CO2 concentration in the atmosphere over a certain period of time

    Ea = total human emission in the atmosphere over that period

    En = total natural emission in the atmosphere over that period

    Un = total CO2 absorbed by natural sinks over that period

    But we must not forget that Un is the total natural sinks uptake, that obviously must account for both "natural" and "human" contributions :

    Un = Unn + Una

    Unn = “natural” carbon that would get absorbed by natural sinks in absence of human emissions (over that period)

    Una = portion of human emitted CO2 that gets absorbed by natural sinks (over that period)

    Thus :
    dC = Ea + En - Unn - Una

    By definition, the variation of CO2 concentration due to just the net “natural” carbon flux is :
    dCn = En - Unn

    so, rearranging earlier equation :
    dCn = dC - Ea + Una

    Since dC is measured to be approximately one half Ea, then this equation shows how nature can be a net emitter (dCn > 0) if the portion of Ea that gets absorbed (= Una) exceeds (approximately) 50% of the total human produced carbon Ea.

    Therefore, the mass balance argument in Cawley’s paper, in this website, and other websites as well, is wrong, and does not prove anything. 

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    Moderator Response:

    [DB]  As has been noted, you've already been through this with other learned individuals who pointed you straight

    It's one thing in life to of necessity to occasionally reinvent the wheel.

    There's no need to reinvent the flat tire.

    Continuing to tilt against the iron windmill of science with a wet paper lance is sloganeering and in violation of this site's Comments Policy.  Please familiarize yourself with it and construct any future comments here to adhere to it.  And above all else, when given good advice such as reading technical material to gain a background understanding of a matter, please avail yourself of the opportunity.

  18. Max:

    You've been through all this over at AndThenTheresPhysics:

    You are just as wrong here as you were there.

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  19. There's a well-known physical argument for understanding why the airborne fraction of CO2 hangs around 50% having to do with diffusional random walk.  When CO2 enters the ocean, it can either diffuse downward or back upward. This is the nature of a pure random walk, with the likelihood of either direction being ~50%.

    So as CO2 moves so slowly to sequestering sites, when it randomly walks back upwards it has a chance to get released back to the atmosphere. 

    Incidentally, this diffusional process explains why the sequestering of CO2 has such a fat-tail for an adjustment time, running to thousands of years.  Again this is well known diffusional physics and I can provide a citation on request. 

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  20. It looks like Max Polo's tenure here has ended, but for the benefit of anyone reading this far and not wanting to read the thread over at AndThenTheresPhysics, here is the lowdown on what Max gets wrong in his post above.

    Max does fine until he gets to the point where he breaks natural uptake into two components, Un = Unn + Una.

    • There is no physical basis to seperate those two fluxes. Max's equation is imply an algebraic distraction.
    • One might divide natural uptake into physically-real components such as ocean vs. terrestrial, biotic vs. chemical, etc. Each of these would react differently over time, because there are different process involved.
    • Each of those simply responds to the current atmospheric CO2 concentration, though - with no differentiation between CO2 that was emitted from natural sources, and CO2 that was emitted from anthropogenic sources.
    • Where Max says "Unn = “natural” carbon that would get absorbed by natural sinks in absence of human emissions", he is wrong. His Unn term is actually carbon that would get absorbed by natural sinks if atmospheric CO2 had not increased. Except CO2 has ncreased. And natural uptake changes as a result. It is now Max's Unn+Una, algebraically, but it is not two different things - it's just natural uptake.

    CO2 uptake varies with time. The Mauna Loa (Keeling) curve shows this clearly when the seasonal cycle is included. It does this for physical reasons, not algebraic ones.

    Mauna Loa CO2 measurements

    The rest of Max's algebraic manipulations are meaningless. There is only one "natural uptake" term that can be used: Max's Un. And Un>En, so nature is a net carbon sink, not a source.

    Max's "nature can be a net emitter" only applies when you fail to include a portion of the natural uptake, which is exacly what Max has done (his Una term). It's like saying "my gambling debts are not draining my bank account, because my bank account shows a net increase if I ignore my gambling expenses". There is a pyschololgical term for what that gambler is thinking.

     

     

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